Doctoral Dissertations

Abstract

"The electrochemical reduction of BrO⁻₃ was studied on a stationary Hg electrode in neutral and basic solutions containing K⁺, Na⁺, and L⁺. Coulombic efficiency studies showed Br⁻ to be the predominant reduction product. The steady state kinetic parameters include Tafel slopes of ca. -0.120 V, approximate first order activity dependences for both BrO⁻₃ and the accompanying cation, and no pH dependence. A reaction scheme is proposed which involves BrO⁻₃ "bridged" to the electrode by the accompanying cation. It is suggested that the "bridging" is a result of ion-pairing in the electrical double-layer"--Abstract, page 1.

Advisor(s)

Johnson, James W., 1930-2002

Committee Member(s)

Strunk, Mailand R., 1919-2008
James, William Joseph
Mayhan, Kenneth G.
Park, Efton

Department(s)

Chemical and Biochemical Engineering

Degree Name

Ph. D. in Chemical Engineering

Publisher

University of Missouri--Rolla

Publication Date

1973

Pagination

viii, 79 pages

Note about bibliography

Includes bibliographical references (page 23).

Rights

© 1973 Jaw-Shin Chang, All rights reserved.

Document Type

Dissertation - Open Access

File Type

text

Language

English

Subject Headings

Electrolytic reductionBromate -- AnalysisReaction mechanisms (Chemistry) -- Design

Thesis Number

T 2774

Print OCLC #

6034335

Electronic OCLC #

912890416

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