Doctoral Dissertations
Abstract
"The coupling of free carriers and lattice vibrational modes is studied in CdS and InSb by room temperature far infrared reflectance measurements. When the free carrier concentration is such that the plasma frequency is at or near the longitudinal optical mode frequency it is shown that while the transverse modes remain fixed, the longitudinal modes mix with the plasma mode and are shifted in a manner similar to that described by Varga in 1965. Using the dielectric function for the coupled system permits the determination of electron effective masses by reflectance measurements with lattice effects excluded. This method allows one to investigate the frequency shifts and effective mass values on crystals in which the mobility varies by more than an order of magnitude as demonstrated by the analysis of both CdS and InSb. In the case of CdS where the polaron coupling constant is large enough to have noticeable effects, account is taken of the polaron mass and of the additional absorption in the plasma mode at frequencies above the longitudinal optical phonon frequency"--Abstract, page i.
Advisor(s)
Bell, Robert John, 1934-
Committee Member(s)
Hultside, Roland A.
Parks, William F.
Foote, Joe R.
Hill, Otto H.
Gerson, Robert, 1923-2013
Tefft, Wayne E., 1929-1973
Department(s)
Physics
Degree Name
Ph. D. in Physics
Sponsor(s)
United States. Bureau of Mines
Publisher
University of Missouri--Rolla
Publication Date
1969
Pagination
iv, 52 pages
Note about bibliography
Includes bibliographical references (pages 46-48).
Rights
© 1969 Thomas Joseph McMahon, All rights reserved.
Document Type
Dissertation - Open Access
File Type
text
Language
English
Subject Headings
Lattice dynamicsNanostructures -- Optical propertiesPhononsPlasmons (Physics)
Thesis Number
T 2231
Print OCLC #
6007172
Electronic OCLC #
806959830
Recommended Citation
McMahon, Thomas Joseph, "Longitudinal optical phonon-plasmon coupling in ionic semiconductors" (1969). Doctoral Dissertations. 1877.
https://scholarsmine.mst.edu/doctoral_dissertations/1877