Doctoral Dissertations

Abstract

"This dissertation consists of four sections. The first part is a temperature dependent X-ray study of the lattice parameters of BiFeo₃. The synthesis and subsequent X-ray characterization of BiCo₃, BiAlO₃, BiMnO₃ , BiScO₃, BiCo₁₋ₓFeₓO₃ , and BiAl₁₋ₓFeₓO₃ are reported in the second part. These compounds all crystallize in the body centered cubic (BCC) structure with a~10.2Å. Single crystal Precession and Weissenberg photographs confirmed the BCC structure. In part three, the results of the magnetic studies on BiCoO₃ and biAl.₉FE.₁ are presented. The magnetic data for BiCoO₃ are substantiated by X-ray thermal expansion studies. In the last part the compound BiCo.₉FE.₁O₃ is examined in some detail. The magnetic studies are substantiated by the X-ray thermal expansion results"--Abstract, page iii.

Advisor(s)

Robertson, B. Ken
James, William Joseph

Committee Member(s)

Biolsi, Louis, Jr.
Gerson, Robert, 1923-2013
Straumanis, Martin E., 1898-1973

Department(s)

Chemistry

Degree Name

Ph. D. in Chemistry

Publisher

University of Missouri--Rolla

Publication Date

1971

Journal article titles appearing in thesis/dissertation

  • The precision determination of the lattice parameters and the coefficients of thermal expansion of BiFeO₃
  • The synthesis and X-ray characterization of a new class of BiMO₃ magnetic compounds

Pagination

ix, 99 pages

Note about bibliography

Includes bibliographical references.

Rights

© 1971 Joseph Donato Bucci, All rights reserved.

Document Type

Dissertation - Open Access

File Type

text

Language

English

Subject Headings

PerovskiteLattice dynamicsX-rays -- DiffractionBody-centered cubic metals

Thesis Number

T 2609

Print OCLC #

6038007

Electronic OCLC #

876047856

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Chemistry Commons

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