Doctoral Dissertations
Abstract
"Metallic glass alloys possess superior corrosion resistance in comparison with the crystalline state of the same alloy due to their chemical and non-crystalline structural homogeneity. The high critical quenching rate required for synthesizing metallic glass alloys demands innovative engineering solutions to allow the commercial production of metallic glass alloys as structural materials.
The purpose of this research is to produce aluminum-based amorphous metallic coatings on aluminum alloy plates using an atmospheric plasma spray (APS) technique to form the corrosion resistant barrier coating. The corrosion resistance of APS coatings tested in a neutral salt-fog chamber showed that the coating performance was dependent on the crystallinity, coating permeability and composition.
The microstructures of the coating produced with the alloy with the highest glass forming ability, Al85Y8Ni5CO2 exhibited mixtures of amorphous and nanocrystalline α-Al particles. A combination of calorimetric and morphological investigations, using melt- spun ribbons with different compositions and quench rates, revealed the presence of yttrium-lean Al85+xY8-xNi5CO2 (x > 0) type amorphous phases, and such investigations explained the nucleation of nanocrystalline α-Al particles during the APS process. The chemical inhomogeneity of the APS coating originated from the local chemical distribution of the milled powder, insufficient plasma energy input and different powder flight paths within the plasma stream. However, the presence of multi-compositional amorphous phases with the associated morphologies of nanocrystalline α-Al particles hinted at significance of atomic clustering upon forming the amorphous phase"--Abstract, page iii.
Advisor(s)
Van Aken, David C.
Miller, F. Scott, 1956-
Committee Member(s)
O'Keefe, Matthew
Hilmas, Greg
Schuman, Thomas P.
Department(s)
Materials Science and Engineering
Degree Name
Ph. D. in Materials Science and Engineering
Publisher
University of Missouri--Rolla
Publication Date
Fall 2005
Journal article titles appearing in thesis/dissertation
- Salt fog corrosion testing of Al-Y-Co based nanocrystalline and amorphous coatings produced by atmospheric plasma spray
- Aluminum-based nanocrystalline coatings produced by atmospheric plasma spray
- Microstructural analysis of plasma sprayed Al-based amorphous alloys: A comparison with melt-spinning technique
Pagination
xvii, 107 pages
Note about bibliography
Includes bibliographical references.
Rights
© 2005 Yoshihide Kato, All rights reserved.
Document Type
Dissertation - Restricted Access
File Type
text
Language
English
Subject Headings
Plasma sprayingMetallic glassesGlass-ceramicsMelt spinningCrystallization -- Industrial applicationsAmorphous substancesAlloys
Thesis Number
T 8831
Print OCLC #
68810561
Electronic OCLC #
1088728510
Recommended Citation
Kato, Yoshihide, "Plasma spraying of aluminum-based glass forming alloys" (2005). Doctoral Dissertations. 1611.
https://scholarsmine.mst.edu/doctoral_dissertations/1611
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