Abstract
Engineered Nanoparticles (ENPs) Have Been Increasingly Used in Agricultural Operations, leading to an Urgent Need for Robust Methods to Analyze Co-Occurring ENPs in Plant Tissues. in Response, This Study Advanced the Simultaneous Extraction of Coexisting Silver, Cerium Oxide, and Copper Oxide ENPs in Lettuce Shoots and Roots using Macerozyme R-10 and Analyzed Them by Single-Particle Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Additionally, the Standard Stock Suspensions of the ENPs Were Stabilized with Citrate, and the Long-Term Stability (Up to 5 Months) Was Examined for the First Time. the Method Performance Results Displayed Satisfactory Accuracies and Precisions and Achieved Low Particle Concentration and Particle Size Detection Limits. Significantly, the Oven Drying Process Was Proved Not to Impact the Properties of the ENPs; Therefore, Oven-Dried Lettuce Tissues Were Used in This Study, Which Markedly Expanded the Applicability of This Method. This Robust Methodology Provides a Timely Approach to Characterize and Quantify Multiple Coexisting ENPs in Plants.
Recommended Citation
L. Xu et al., "Advancing Simultaneous Extraction and Sequential Single-Particle ICP-MS Analysis for Metallic Nanoparticle Mixtures in Plant Tissues," Journal of Agricultural and Food Chemistry, vol. 72, no. 19, pp. 11251 - 11258, American Chemical Society, May 2024.
The definitive version is available at https://doi.org/10.1021/acs.jafc.3c09783
Department(s)
Civil, Architectural and Environmental Engineering
Second Department
Chemistry
Third Department
Chemical and Biochemical Engineering
International Standard Serial Number (ISSN)
1520-5118; 0021-8561
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2024 American Chemical Society, All rights reserved.
Publication Date
15 May 2024
PubMed ID
38699857
Included in
Analytical Chemistry Commons, Architectural Engineering Commons, Biochemical and Biomolecular Engineering Commons, Civil and Environmental Engineering Commons
Comments
National Science Foundation, Grant 1900022