Abstract
The Diffusion and Permeation Coefficients for He, H2, D2, O2, and N2 in a Variety of Elastomers Were Measured by Simple Manometric Methods. the Elastomers Studied Were Butyl Rubber; Hypalon® 40 and 45; Viton® E60 and GF; Hydrin® 100 and Filled Hydrin® 100; Kraton® G, FG, and KG VTEOS; EPDM; Epoxidized Natural Rubber; and Neoprene. Consistent with Earlier Studies, Elastomers with Higher Glass Transition Temperatures Exhibited Lower Diffusion Coefficients. the Ratio of Diffusion Coefficients of the Hydrogen Isotope Pair Differed from the Purely Molecular‐weight‐based Prediction. Deuterium's Slightly Smaller Size Relative to Hydrogen is Consistent with Observed Deviations from the Molecular‐weight‐based Diffusion Coefficient Ratio. © 1993 John Wiley & Sons, Inc. Copyright © 1993 John Wiley & Sons, Inc.
Recommended Citation
M. W. Fitch et al., "Permeation of Several Gases through Elastomers, with Emphasis on the Deuterium/hydrogen Pair," Journal of Applied Polymer Science, vol. 47, no. 6, pp. 1033 - 1046, Wiley, Jan 1993.
The definitive version is available at https://doi.org/10.1002/app.1993.070470610
Department(s)
Civil, Architectural and Environmental Engineering
International Standard Serial Number (ISSN)
1097-4628; 0021-8995
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Wiley, All rights reserved.
Publication Date
01 Jan 1993