Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex

Author

Chengbao Ni
Troy A. Stich
Gary J. Long, Missouri University of Science and TechnologyFollow
Philip P. Power

Abstract

The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6- iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment. © 2010 The Royal Society of Chemistry.

Recommended Citation

C. Ni et al., "Unusual Magnetic Properties of a Two-coordinate Heteroleptic Linear Cobalt(II) Complex," Chemical Communications, Royal Society of Chemistry, Jan 2010.

The definitive version is available at https://doi.org/10.1039/c001483d

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1359-7345

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2010 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 2010