Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate
Abstract
The salt [CxNH2][HFe3(CO)11]·OEt2 (Cx = cyclohexyl, Et = ethyl) was isolated from Cx2NBBr2/Na2Fe2(CO)8/Et2O and was shown by X-ray diffraction (monoclinic, P21/a: a = 17.449(5), b = 16.345(5), c =13.466(4) Å, β = 118.45(2)0, Z = 4) to contain the expected Cx2NH+2 and HFe3(CO)-11 ions as well as the diethyl ether. In each Cx2NH+2 cation one hydrogen atom is hydrogen bonded to the bridging CO oxygen of the HFe3(CO)11 anion whereas the other hydrogen atom is hydrogen bonded to the diethyl ether. The Mössbauer effect spectral parameters (δ, ΔEQ, Γ, area ratios) of [Cx2NH2][HFe3(CO)11] at 295 and 78 K are closely related to those of Fe3(CO)12. © 1991.
Recommended Citation
R. B. King et al., "Some Studies on Dicyclohexylammonium Hydridoundecacarbonyltriferate," Journal of Organometallic Chemistry, Elsevier, Jan 1991.
The definitive version is available at https://doi.org/10.1016/0022-328X(91)83047-8
Department(s)
Chemistry
International Standard Serial Number (ISSN)
0022-328X
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1991 Elsevier, All rights reserved.
Publication Date
01 Jan 1991
