An Arene-Stabilized Cobalt(I) Aryl: Reactions with CO and NO
The half-sandwich cobalt(I) complex (η6-C7H 8)CoAr*-3,5-iPr2 (Ar*-3,5- iPr2 = -C6H-2,6-(C6H 2-2,4,6-iPr3)2-3,5- iPr2) was synthesized by reduction of [3,5- iPr2Ar*Co(µ-Cl)]2 in toluene. It reacts with CO or NO to afford the unusual complexes [3,5-iPr 2Ar*C(O)Co(CO)] or [3,5-iPr2Ar* N(NO)OCo(NO)2].
H. Lei et al., "An Arene-Stabilized Cobalt(I) Aryl: Reactions with CO and NO," Inorganic Chemistry, vol. 47, no. 22, pp. 10205-10207, American Chemical Society (ACS), Nov 2008.
The definitive version is available at https://doi.org/10.1021/ic8015782
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© 2008 American Chemical Society (ACS), All rights reserved.
01 Nov 2008