Bis[2-(1H-imidazol-2-yl-κN³)-1H-imidazol-3-ium]silver(I) Trinitrate

Author

Shelonda R. Finch
J. P. Harper
Amitava Choudhury, Missouri University of Science and TechnologyFollow
Ekkehard Sinn, Missouri University of Science and TechnologyFollow
Harvest L. Collier, Missouri University of Science and TechnologyFollow

Abstract

The synthesis of the title salt, [Ag(C ₆H ₇N ₄) ₂](NO ₃) ₃, was carried out employing a 1:2 molar ratio of 2,2'-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N - Ag - N = 177.01 (17)°]. The crystal structure displays N - H⋯O and C - H⋯O hydrogen-bonding interactions.

Recommended Citation

S. R. Finch et al., "Bis[2-(1H-imidazol-2-yl-κN³)-1H-imidazol-3-ium]silver(I) Trinitrate," Acta Crystallographica Section E: Structure Reports Online, vol. E67, no. 7, pp. m909 - m909, Wiley-Blackwell, Jul 2011.

The definitive version is available at https://doi.org/10.1107/S1600536811021799

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1600-5368

Document Type

Article - Journal

Document Version

Final Version

File Type

text

Language(s)

English

Rights

© 2011 Wiley-Blackwell, All rights reserved.

Publication Date

01 Jul 2011