Abstract

Students frequently encounter difficulties in learning the vast landscape of electrochemistry. Here are shared examples of methods to demystify electrochemistry based on the extensive experience of the authors. Topics include a perspective on the shape of a voltammogram viewed as Ohm's Law, an extrapolation to electrochemical impedance spectroscopy (EIS), potential axes to identify spontaneous reactions, and select examples from organic and biological electrochemistry. Explained is the rationale behind certain Go To molecules used in electrochemical experiments such as ferrocene, ferricyanide, and other inorganic and organic electroactive molecules. Finally, more than sigmoidal curves are needed to confirm electrocatalysis. The domain of electrochemistry is charted across these disparate topics. The article is dedicated to Diane Smith, an outstanding educator, scholar, and mentor.

Department(s)

Chemistry

Publication Status

Open Access

Keywords and Phrases

electrocatalytic mechanisms; electrochemical impedance; electrochemical redox probes; electrochemistry education; Ohm's Law; Teaching; voltammetry

International Standard Serial Number (ISSN)

1945-7111; 0013-4651

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 IOP Publishing, All rights reserved.

Creative Commons Licensing

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.

Publication Date

01 Jan 2026

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