The Oxidative Decarboxylation Of Polyaminocarboxylic Acidm-VI¹ 1 Part V-See Reference 16. Reaction Of Diethylenetriaminepenta-acetic Acid With Cerium(IV) In Sulphuric Acid Media
Abstract
The oxidation of diethylenetrianunepenta-acetic acid (DTPA) by Ce(IV) in sulphuric add was investigated spectrophotometrically by the stopped-flow technique. The rate of reaction is influenced by the acidity, but can be expressed by a simplified rate law {A figure is presented} At [H2SO4] below 0.75M the reaction proceeds stepwise as shown by formation of a 1:1 Ce(IV)-DTPA complex with measurable rate of formation and decay. At higher acid strengths, the formation of an intermediate is not evident. The rate is maximal in ~ 0.75M sulphuric add. The overall stoichiometry varies with time. © 1972.
Recommended Citation
S. B. Hanna et al., "The Oxidative Decarboxylation Of Polyaminocarboxylic Acidm-VI¹ 1 Part V-See Reference 16. Reaction Of Diethylenetriaminepenta-acetic Acid With Cerium(IV) In Sulphuric Acid Media," Talanta, vol. 19, no. 10, pp. 1097 - 1104, Elsevier, Jan 1972.
The definitive version is available at https://doi.org/10.1016/0039-9140(72)80049-3
Department(s)
Chemistry
International Standard Serial Number (ISSN)
0039-9140
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Elsevier, All rights reserved.
Publication Date
01 Jan 1972
