Preparation And Reactions Of Diazomalonic Esters

Author

B. W. Peace
David S. Wulfman, Missouri University of Science and Technology

Abstract

Diazomalonic esters offer ready access to some classes of geminally disubstituted cyclopropanes,endo-substituted bicyclo[n.1.0] systems, and selectively cyclopropanated polyolefins as well as some classes of olefins bearing ether, sulfide, and halogen substituents.The current scope and limitations of synthesis involving these systems are illustrated.1.Preparation of Diazomalonic Esters 2. Reaction with Saturated C-H Bonds 3. Reactions with Olefins 4. Copper and Copper-Salt Catalysis 5. Reaction with Benzene 6. Reactions with Ethers and Alkyl Sulfides 7.Reactions with Amines 8. Reactions with Sulfoxides 9.Reactions with Thioketones 10.Reactions with Allyl Sulfides and Halides 11. Recent Work.

Recommended Citation

B. W. Peace and D. S. Wulfman, "Preparation And Reactions Of Diazomalonic Esters," Synthesis (Germany), vol. 1973, no. 3, pp. 137 - 145, Thieme Gruppe, Mar 1973.

The definitive version is available at https://doi.org/10.1055/s-1973-22146

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1437-210X; 0039-7881

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Thieme Gruppe, All rights reserved.

Publication Date

01 Mar 1973