The Effect Of Peroxides On The Reactions Of Dimethoxycarbonylcarbene Generated With Soluble Catalysts From Dimethyl Diazomalonate

Abstract

The presence of alkenyl or aryl radicals converts trimethyl phosphite copper(I) iodide into an extremely potent soluble catalyst capable of decomposing diazo-esters cleanly into the corresponding carbenoid species.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0577-6171

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Journal of the Chemical Society D: Chemical Communications, All rights reserved.

Publication Date

01 Jan 1971

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