Abstract
The front cover artwork is provided by Prof. Rainer Glaser's group at the Missouri University of Science and Technology. The image shows one of four potential energy surfaces generated from our rotation-inversion study of tertiary carbamates and highlights two of the eight possible transition state pathways between two ensembles of E- and Z-minima. In the context of synthetic studies of fluorinated carbamates R1 O-CO-N(R2 )CH2 CF3, we unexpectedly observed two sets of 13C NMR quartets for the CF3 group and we needed to understand their origin. Read the full text of the Research Article at 10.1002/cphc.2022005442.
Recommended Citation
B. Jameson and R. Glaser, "Rotation-Inversion Isomerization of Tertiary Carbamates: Potential Energy Surface Analysis of Multi-Paths Isomerization using Boltzmann Statistics," Chemphyschem : a European journal of chemical physics and physical chemistry, vol. 24, no. 1, p. e202200893, Wiley, Jan 2023.
The definitive version is available at https://doi.org/10.1002/cphc.202200893
Department(s)
Chemistry
International Standard Serial Number (ISSN)
1439-7641
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Wiley, All rights reserved.
Publication Date
03 Jan 2023
PubMed ID
36594716
Comments
National Science Foundation, Grant No. OAC-191978 and #1665487