Seleno- and Tellurocarbenium Ions

Abstract

α-Chalcogeno substituted carbenium salts [(RX) 3C] + PF6 - (X = S, Se, Te; R = 2, 4, 6-/Pr 3C6H2) obtained from reaction of the copper complexes [(bipy)CuXR] with CBfy are stabilized to the same extent; but the electronic mechanism is very different.

Department(s)

Chemistry

Keywords and Phrases

Carbenium Ions; Tellurium; Selenium; Stability; Ab initio calculations; Structures

International Standard Serial Number (ISSN)

1463-0095

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1997 Librapharm Ltd., All rights reserved.

Publication Date

01 Jan 1997

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