Multifurcated Halogen Bonding Involving Ph-Cl⋯H-CPh=N-R' Interactions and Its Relation to Idioteloamphiphile Layer Architecture

Author

Rainer Glaser, Missouri University of Science and TechnologyFollow
Richard F. Murphy
Yongqiang Sui
Charles Leslie Barnes
SungHoon Kim

Abstract

The presence of halogen bonding between a chloroarene and an aldazine C-H bond, i.e. Ph-Cl⋯H-CPh=N-R', makes all the difference in the crystal structure of 4-chlorobenzaldazine (1, R = H) and causes an idioteloamphiphile layer architecture (flat with longitudinal offset) that features multifurcated halogen bonding and that differs drastically from the one in 4-chloroacetophenone azine (2, R = CH₃).

Recommended Citation

R. Glaser et al., "Multifurcated Halogen Bonding Involving Ph-Cl⋯H-CPh=N-R' Interactions and Its Relation to Idioteloamphiphile Layer Architecture," CrystEngComm, vol. 8, no. 5, Royal Society of Chemistry, Jan 2006.

The definitive version is available at https://doi.org/10.1039/b601467d

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1466-8033

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2006 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 2006