Interfacial Bonding and Optical Transmission for Transparent Fiberglass/Poly(Methyl Methacrylate) Composites

Abstract

Evidence is presented relating the interfacial bonding strength and the optical transmission of transparent glass fiber reinforced PMMA composites. The temperature dependent (20° to 50°C) optical transmission of composites that contained uncoated 13 μm glass fibers and 13 μm glass fibers coated with divinyltetramethyl disilazane or 3-(trimethoxysilyl)propyl methacrylate was found to decrease in the same order as the bond strength of the PMMA/glass fiber interface, namely, trimethoxy silane coated fiber, disilazane coated fiber, and uncoated fiber. SEM photographs showed similar fracture surfaces, clean fiber pull-out, and no apparent bonding of the glass fiber to the PMMA for the composites containing uncoated and disilazane coated fiber, whereas, the composite containing trimethoxy silane coated fiber showed virtually no clean fiber pullout. Additional evidence for differences in the bonding strength is seen in the degradation (penetration of water and fiber whitening) on aging at 23°C in air or water for composites containing uncoated fiber (most degradation), disilazane coated fiber (slight degradation), and trimethoxy silane coated fiber (no degradation). The optical transmission between 20° and 30°C at 600 to 800 nm for the composite containing trimethoxy silane coated fiber decreased the least with increasing temperature (from ~85% to 70%) while the composite containing uncoated fiber decreased the most (from ~85% to 32%).

Department(s)

Chemistry

Second Department

Materials Science and Engineering

International Standard Serial Number (ISSN)

0272-8397

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1995 John Wiley & Sons Inc., All rights reserved.

Publication Date

01 Apr 1995

Link to Full Text

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