NMR Studies of the Kinetics of Homogeneously Catalyzed Hydrogénations Using Parahydrogen Induced Polarization at Variable Pressure
Abstract
Quantitative evaluation of Parahydrogen Induced Polarization (PHIP) experiments provides for the determination of kinetic data of homogeneously catalyzed hydrogénations. Especially developed NMR probes facilitate investigations at reproducible reaction conditions and constant hydrogénation rates. Rate equations, describing the experimentally achieved steady state kinetics, are used to determine the pressure dependent ratio between free and complexed catalyst in the reactive solution during the hydrogénation. A method is presented to determine the rate constants of the catalytic cycle of such hydrogénations, which follow the hydride route.
Recommended Citation
K. Woelk and J. Bargon, "NMR Studies of the Kinetics of Homogeneously Catalyzed Hydrogénations Using Parahydrogen Induced Polarization at Variable Pressure," Zeitschrift für Physikalische Chemie, vol. 182, no. Part_1_2, pp. 155 - 165, Oldenbourg Wissenschaftsverlag GmbH, Jan 1993.
The definitive version is available at https://doi.org/10.1524/zpch.1993.182.Part_1_2.155
Department(s)
Chemistry
Keywords and Phrases
CIDNP; Hydrogenation reactions; Parahydrogen; PHIP
International Standard Serial Number (ISSN)
0942-9352
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1993 Oldenbourg Wissenschaftsverlag GmbH, All rights reserved.
Publication Date
01 Jan 1993
