Onium-Poly(Hydrogen Fluorides): Convenient Ionic Liquids for Fluorination and Acid Catalysis
Abstract
Onium polyhydrogen fluorides as room temperature ionic liquids (RTILs) have found a wide variety of applications in organic chemistry. They are used as ionic solvents, fluorinating agents and as Bronsted acid catalysts in organic synthesis. A variety of industrially important reactions such as fluorinations, halofluorinations, electrophilic alkylations, nitrations, and hydrocarbon isomerization reactions have been carried out using them. This short review covers some slected salient recent applications of these intriguing ionic liquids.
Recommended Citation
G. A. Olah et al., "Onium-Poly(Hydrogen Fluorides): Convenient Ionic Liquids for Fluorination and Acid Catalysis," ACS Symposium Series, vol. 950, pp. 36 - 57, American Chemical Society (ACS), Jan 2007.
The definitive version is available at https://doi.org/10.1021/bk-2007-0950.ch004
Department(s)
Chemistry
International Standard Book Number (ISBN)
978-0841274075
International Standard Serial Number (ISSN)
0097-6156
Document Type
Book - Chapter
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2007 American Chemical Society (ACS), All rights reserved.
Publication Date
18 Jan 2007
