Friedel-Crafts Reactions
Abstract
Recent trends in Friedel-Crafts and related electrophilic reactions, using a variety of Lewis and Brønsted acid catalysts, are comprehensively reviewed. The Friedel-Crafts reactions include alkylations, acylations, hydroxylations, nitrations, halogenations, aminations, sulfuration, sulfinylation, and sulfonylation of aromatic and olefinic hydrocarbons. The nature and types of acid catalysts are discussed, including superelectrophilic activation. Representative stereoselective Friedel-Crafts alkylations are also described.
Recommended Citation
P. Reddy and G. K. Prakash, "Friedel-Crafts Reactions," Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Apr 2013.
The definitive version is available at https://doi.org/10.1002/0471238961.0618090515120108.a01.pub2
Department(s)
Chemistry
Keywords and Phrases
Freidel-Crafts Reactions; Lewis and Bronsted Acid Catalysts; Electrophilic Reactions
Document Type
Book - Chapter
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2013 John Wiley & Sons, All rights reserved.
Publication Date
19 Apr 2013