Changes at the Iodine Nucleus in 1-iodopropane when One Hydrogen at the Carbon-3 Position Is Replaced by Fluorine

Author

Garry S. Grubbs, Missouri University of Science and TechnologyFollow
William C. Bailey
Stephen A. Cooke

Abstract

Pure rotational spectra pertaining to 1-fluoro-3-iodopropane have been recorded using a Search Accelerated Correct Intensity Fourier Transform Microwave Spectrometer. Two conformers were observed and a total of 148 transitions recorded between 8 and 12 GHz. the complete iodine quadrupole coupling tensor has been determined for both observed conformers of 1-fluoro-3-iodopropane and are compared to those values for 1-iodopropane. Quantum chemical calculations were performed on the title molecule which greatly facilitated the spectral assignments and analyses.

Recommended Citation

G. S. Grubbs et al., "Changes at the Iodine Nucleus in 1-iodopropane when One Hydrogen at the Carbon-3 Position Is Replaced by Fluorine," Chemical Physics Letters, vol. 447, no. 1-3, pp. 37 - 40, Elsevier, Jan 2009.

The definitive version is available at https://doi.org/10.1016/j.cplett.2009.06.059

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0009-2614

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2009 Elsevier, All rights reserved.

Publication Date

01 Jan 2009