The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis
Abstract
A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J=1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v0,1,2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115Sn16O, 117Sn16O and 119Sn16O. the nuclear spin-rotation constant CI(Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. a multi-isotopomer analysis, including data from the 120Sn17O and 120Sn18O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.
Recommended Citation
C. T. Dewberry et al., "The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn Nuclear Spin-rotation Constants in Stannous Monoxide, SnO, and a New Multi-isotopomer Analysis," Journal of Molecular Spectroscopy, vol. 248, no. 1, pp. 20 - 25, Elsevier, Jan 2008.
The definitive version is available at https://doi.org/10.1016/j.jms.2007.11.009
Department(s)
Chemistry
International Standard Serial Number (ISSN)
0022-2852
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2008 Elsevier, All rights reserved.
Publication Date
01 Jan 2008
