A New Type of Polycyclophosphidochromium Cluster, [(Cp)Cr(CO)₂]₅P₁₀ (Cp = Η⁵-C₅H₅)

Alternative Title

First observation of polycylic P-to-M coordination

Author

Lai Yoong Goh
Richard C. S. Wong
Ekkehard Sinn, Missouri University of Science and TechnologyFollow

Abstract

The co-thermolysis of [(Cp)Cr(CO)3]2 (Cp = η5-C5H5) with P4 forms [(Cp)Cr(CO)2]5P10, a new paramagnetic structure with a P10 core, which represents the first example of polycyclic phosphorus-to-metal coordination.

Recommended Citation

L. Y. Goh et al., "A New Type of Polycyclophosphidochromium Cluster, [(Cp)Cr(CO)₂]₅P₁₀ (Cp = Η⁵-C₅H₅)," Journal of the Chemical Society, Chemical Communications, Royal Society of Chemistry, Jan 1990.

The definitive version is available at https://doi.org/10.1039/C39900001484

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1990 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 1990