Organically Templated Mixed-Valent Iron-Sulfates Possessing Kagome and Other Types of Layered Networks

Author

Geo L. Paul
Amitava Choudhury, Missouri University of Science and TechnologyFollow
Echur Varadadesikan Sampathkumaran
Chintamani Nagesa Ramachandra Rao

Abstract

A perfect Kagomé lattice is displayed by the mixed-valent layered structure of [HN(CH₂)₆NH][Fe^III- Fe₂^IIF₆(SO₄)₂] · [H₃O] (see picture), in which 100% of the iron sites are occupied. The complex exhibits unusual magnetic properties and both magnetic frustration and ferrimagnetic behavior are observed.

Recommended Citation

G. L. Paul et al., "Organically Templated Mixed-Valent Iron-Sulfates Possessing Kagome and Other Types of Layered Networks," Angewandte Chemie International Edition, vol. 41, no. 22, pp. 4297 - 4300, Wiley-VCH Verlag, Nov 2002.

The definitive version is available at https://doi.org/10.1002/1521-3773(20021115)41:22<4297::AID-ANIE4297>3.0.CO;2-E

Department(s)

Chemistry

Keywords and Phrases

Crystal lattices; Iron compounds; Magnetic properties, Layered networks, Organic compounds, ferromagnetic material; ferrous sulfate, article; chemical analysis; chemical structure; complex formation; magnetism; materials testing; structure analysis; Hydrothermal synthesis; Iron; Kagomé lattice; Layered structures; Magnetic properties

International Standard Serial Number (ISSN)

1433-7851

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2002 Wiley-VCH Verlag, All rights reserved.

Publication Date

01 Nov 2002