An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions

Author

Amitava Choudhury, Missouri University of Science and TechnologyFollow
Sharma Neeraj
Srinivasan R. Natarajan
Chintamani Nagesa Ramachandra Rao

Abstract

Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH₂][Co_3.5(PO₄)₃] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.

Recommended Citation

A. Choudhury et al., "An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions," Angewandte Chemie International Edition, vol. 39, no. 17, pp. 3091 - 3093, Wiley-VCH Verlag, Sep 2000.

The definitive version is available at https://doi.org/10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6

Department(s)

Chemistry

Keywords and Phrases

Cobalt Complex; Phosphate, Article; Chemical Bond; Chemical Structure; Conformational Transition; Magnetism; Structure Analysis; Synthesis; Temperature; Cobalt; Magnetic Properties; Solid-State Structures

International Standard Serial Number (ISSN)

1433-7851

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2000 Wiley-VCH Verlag, All rights reserved.

Publication Date

01 Sep 2000