Dalton Communication: Crystal Structure and Oxo-transfer Properties of [NH₄]₂[WᵛᴵO₂{O₂CC(S)Ph₂}₂]
Abstract
The complex [NH4]2[WVIO2O 2CC(S)Ph22] is the first example of a non-dithiolene tungsten complex capable of oxidising benzoin to benzil in methanol; the reduced complex product formed, presumably a monomeric WVIO species, was reoxidised with nitrate ions, regenerating the starting WVIO2 complex which then acts as a true homogeneous catalyst.
Recommended Citation
A. Cervilla et al., "Dalton Communication: Crystal Structure and Oxo-transfer Properties of [NH₄]₂[WᵛᴵO₂{O₂CC(S)Ph₂}₂]," Journal of the Chemical Society, Dalton Transactions, Royal Society of Chemistry, Jan 1994.
The definitive version is available at https://doi.org/10.1039/DT9940003511
Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1994 Royal Society of Chemistry, All rights reserved.
Publication Date
01 Jan 1994
