Synthesis of a New Class of Mo-Fe-S Clusters Containing the MoS₂Fe₂ Unit

Abstract

A new synthetic route to Mo-Fe-S clusters related to nitrogenase has been developed, in which the bridging sulfides originate with the iron reagent (rather than with MoS2- 4, as is the case for other known Mo-Fe-S clusters). This route produces clusters containing the novel Mo(μ3-S)2Fe2 structural unit, which is only the third known type of such a cluster (in addition to those containing the “linear” MoS2Fe and “cubane” MoFe3S4 units). Reaction of the [Fe2S2(CO)6]2- dianion with MoCl5 has been found to produce at least four new clusters, including two Fe-S carbonyl clusters and two novel Mo-Fe-S clusters, including I. Complex I, isolated as the Ph4As+ salt, has been identified as the [MoOFe5S6(CO)12]2- dianion by a single-crystal structure determination: space group P21/n, monoclinic, Z = 4; a = 14.127(6) Å, b = 17.818(5) Å, c = 26.802(18) Å, β = 94.51(2)°, V = 6726 Å3; current R = 8.9%, Rw = 9.4%; 2768 unique data with F2 > 3σ(F2). Complex I can also be prepared in higher yield from the reaction of MoOCl3·2THF with excess [Fe2S2(CO)6]2- or [Fe4S4(CO)12]2-. © 1986.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0277-5387

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1986 Elsevier, All rights reserved.

Publication Date

01 Jan 1986

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