X-ray Absorption Fine Structure Study of the Bound State Electronic Transitions at the Vanadium K and L Edges in Low Symmetry, Molecular, Vanadium-(IV) and -(V) Complexes with Oxyoxime and Oxyoximate Ligands
Abstract
A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of V V in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η 2-N-O groups.
Recommended Citation
D. Collison and C. D. Garner and J. Grigg and C. M. McGrath and J. F. Mosselmans and E. Pidcock and M. D. Roper and J. M. Seddon and E. Sinn and P. A. Tasker and G. Thornton and J. F. Walsh and N. A. Young, "X-ray Absorption Fine Structure Study of the Bound State Electronic Transitions at the Vanadium K and L Edges in Low Symmetry, Molecular, Vanadium-(IV) and -(V) Complexes with Oxyoxime and Oxyoximate Ligands," Journal of the Chemical Society, Dalton Transactions, Royal Society of Chemistry, Jan 1998.
The definitive version is available at https://doi.org/10.1039/A800568K
Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1998 Royal Society of Chemistry, All rights reserved.
Publication Date
01 Jan 1998
