Polymerization in Water-in-oil Microemulsion Systems - 1
Phase diagrams for monomer (methyl acrylate containing microemulsions) are shown and described. Polymerizations of a series of microemulsified minomer reveals the expected linear dependence of a given ratio for pentanol acting as a chain transfer agent and giving a value of 5. 1 multiplied by 10** minus **4 for C//s. No break in molecular weight behavior was shown as a result of micellization at higher water contents. a comparison of molecular weights obtained by various classical methods (solution, emulsion, bulk) are also given.
J. O. Stoffer and T. L. Bone, "Polymerization in Water-in-oil Microemulsion Systems - 1," Journal of Polymer Science Part A-1: Polymer Chemistry, Wiley-Blackwell, Jan 1980.
The definitive version is available at https://doi.org/10.1002/pol.1980.170180822
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© 1980 Wiley-Blackwell, All rights reserved.