Oxygenation of Hydrocarbons Mediated by Mixed-valent Basic Iron Trifluoroacetate and Valence-separated Component Species under Gif-type Conditions Involves Carbon- and Oxygen-centered Radicals
Abstract
Hydrogen-atom abstraction by hydroxyl radicals takes place to generate both tert- and sec-adamantyl radicals in Gif-type oxygenation of adamantane by H2O2 in pyridine/trifluoroacetic acid when the reaction is mediated by [Fe(O2CCF3)2(py)4] or [Fe2O(O2CCF3)4(py)6], which are formed by dissociation of [Fe3O(O2CCF3)6- (L)3] in pyridine (L = H2O, DMSO; see scheme).
Recommended Citation
A. E. Tapper et al., "Oxygenation of Hydrocarbons Mediated by Mixed-valent Basic Iron Trifluoroacetate and Valence-separated Component Species under Gif-type Conditions Involves Carbon- and Oxygen-centered Radicals," Angewandte Chemie International Edition, vol. 39, no. 13, pp. 2343 - 2346, Wiley-VCH Verlag, Jul 2000.
The definitive version is available at https://doi.org/10.1002/1521-3773(20000703)39:13<2343
Department(s)
Chemistry
Keywords and Phrases
Hydrocarbon; Trifluoroacetic Acid; chemical Reaction; Chemical Structure; Oxidation; Structure Analysis
International Standard Serial Number (ISSN)
1433-7851
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2000 Wiley-VCH Verlag, All rights reserved.
Publication Date
01 Jul 2000
