Synthesis and X-ray Crystal Structures of the First Tetrahedral Osmium(IV) Compounds, Tetrakis(cyclohexyl)osmium(IV) and Tetrakis(o-methylphenyl)osmium(IV)

Author

Robert P. Tooze
Pericles Stavropoulos, Missouri University of Science and TechnologyFollow
Majid Motevalli
Michael B. Hursthouse
Geoffrey Wilkinson

Abstract

The compounds OsR₄, R = cyclohexyl, o-methylphenyl, have been isolated by the interaction of the appropriate Grignard reagents with Os ₂(O₂CMe)₄Cl₂ and OsO₄ respectively; both complexes have been characterized by X-ray crystallography.

Recommended Citation

R. P. Tooze et al., "Synthesis and X-ray Crystal Structures of the First Tetrahedral Osmium(IV) Compounds, Tetrakis(cyclohexyl)osmium(IV) and Tetrakis(o-methylphenyl)osmium(IV)," Journal of the Chemical Society, Chemical Communications, no. 16, pp. 1139 - 1140, Royal Society of Chemistry, Jan 1985.

The definitive version is available at https://doi.org/10.1039/C39850001139

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1985 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 1985