Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si-H Bond of Silanes

Author

Les A. Dakin
Patricia C. Ong
James S. Panek
Richard J. Staples
Pericles Stavropoulos, Missouri University of Science and TechnologyFollow

Abstract

Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si− H Bond of Silanes" />

Recommended Citation

L. A. Dakin et al., "Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si-H Bond of Silanes," Organometallics, vol. 19, no. 15, pp. 2896 - 2908, American Chemical Society (ACS), Jul 2000.

The definitive version is available at https://doi.org/10.1021/om0003786

Department(s)

Chemistry

Keywords and Phrases

Catalyst Activity; Chemical Bonds; Copper Compounds; Electronic Properties; Molecular Structure; Silicon Compounds; Stoichiometry; Ligand; Organometallics

International Standard Serial Number (ISSN)

0276-7333

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2000 American Chemical Society (ACS), All rights reserved.

Publication Date

01 Jul 2000