Abstract

Water splitting producing hydrogen and oxygen gases appears promising in view of the increasing need of renewable energy sources and storage strategies. Investigation of stable and highly efficient electrocatalysts for oxygen evolution reaction (OER) is targeted in this study at cobalt oxide nanoparticle modified glassy carbon (nano-CoOx/GC) electrodes. The effect of the preparation (Tp) and measuring temperature (Tm) on the electrocatalytic activity of nano-CoOx/GC towards the OER is investigated under various operating conditions. Linear sweep voltammetry (LSV), cyclic voltammetry (CV) as well as SEM and XRD techniques were used to probe the electrocatalytic and morphological characteristics of nano-CoOx prepared under various conditions. Increasing Tp and/or Tm results in improving the kinetics and electrocatalytic activity of the proposed anodes towards the OER as demonstrated in the value of the onset potential of the OER and the OER currents recorded at a fixed potential. The morphology as well as the surface characterization of the prepared catalyst are reported herein and evaluated.

Department(s)

Chemical and Biochemical Engineering

Publication Status

Open Access

Keywords and Phrases

Electrocatalysis; Hydrogen evolution; Nanoparticles; Oxygen evolution; Water splitting

International Standard Serial Number (ISSN)

1452-3981

Document Type

Article - Journal

Document Version

Final Version

File Type

text

Language(s)

English

Rights

© 2023 Elsevier, All rights reserved.

Creative Commons Licensing

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.

Publication Date

01 Jan 2020

Share

 
COinS