Abstract
The plasma polymerization of triallyl phosphine in order to form a crosslinked polymer thin film is described. The plasma polymer thin film has been characterized and shown to contain a high proporation of C=C and P groups conserved from the monomer. The accessibility of the phosphine groups has been demonstrated by reaction with O2, NO, Ni(CO)4, and Fe(CO)5. Reaction with O2, and NO results in a P=O moiety formation. Reaction with the gaseous metal carbonyls results in fixation of the metal via complexation by the P groups as a result of exchange with CO ligand(s). This illustrates the utility of a ligand donor group containing plasma polymer as an avenue for the formation of a single phase transition metal containing plasma polymer. Copyright © 1992 John Wiley & Sons, Inc.
Recommended Citation
S. D. Clymer et al., "Triallylphosphine Plasma Polymerization And Reaction Of The Product With Volatile Transition Metal Compounds," Journal of Applied Polymer Science, vol. 45, no. 1, pp. 135 - 145, Wiley, Jan 1992.
The definitive version is available at https://doi.org/10.1002/app.1992.070450116
Department(s)
Chemical and Biochemical Engineering
Publication Status
Full Access
International Standard Serial Number (ISSN)
1097-4628; 0021-8995
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Wiley, All rights reserved.
Publication Date
01 Jan 1992
