"The Exchange Of Chloro And Ethoxy Groups Upon The Addition Of Dimethyl" by B. Suryanarayanan, B. W. Peace et al.
 

The Exchange Of Chloro And Ethoxy Groups Upon The Addition Of Dimethylchlorosilane To Vinyldimethylethoxysilane

Abstract

The addition of dimethylchlorosilane to vinyldimethylethoxysilane in the presence of chloroplatinic acid yielded 1,2-bis(dimethylchlorosilyl)ethane, 1-(dimethylchlorosilyl)-2-(dimethylethoxysilyl)ethane and 1,2-bis(dimethylethoxysilyl)ethane. The formation of three products is explained on the basis of chloro-ethoxy exchange reactions. Equilibration of the dimethylchlorosilane-vinyldimethylethoxysilane system was investigated using 1H NMR and gas-liquid chromatography. The equilibrium constants indicated near random behavior for the substituent exchange. © 1973.

Department(s)

Chemical and Biochemical Engineering

International Standard Serial Number (ISSN)

0022-328X

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Elsevier, All rights reserved.

Publication Date

01 Jul 1973

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