The Exchange Of Chloro And Ethoxy Groups Upon The Addition Of Dimethylchlorosilane To Vinyldimethylethoxysilane

Author

B. Suryanarayanan
B. W. Peace
Kenneth G. Mayhan, Missouri University of Science and Technology

Abstract

The addition of dimethylchlorosilane to vinyldimethylethoxysilane in the presence of chloroplatinic acid yielded 1,2-bis(dimethylchlorosilyl)ethane, 1-(dimethylchlorosilyl)-2-(dimethylethoxysilyl)ethane and 1,2-bis(dimethylethoxysilyl)ethane. The formation of three products is explained on the basis of chloro-ethoxy exchange reactions. Equilibration of the dimethylchlorosilane-vinyldimethylethoxysilane system was investigated using 1H NMR and gas-liquid chromatography. The equilibrium constants indicated near random behavior for the substituent exchange. © 1973.

Recommended Citation

B. Suryanarayanan et al., "The Exchange Of Chloro And Ethoxy Groups Upon The Addition Of Dimethylchlorosilane To Vinyldimethylethoxysilane," Journal of Organometallic Chemistry, vol. 55, no. 1, pp. 65 - 71, Elsevier, Jul 1973.

The definitive version is available at https://doi.org/10.1016/S0022-328X(00)84037-1

Department(s)

Chemical and Biochemical Engineering

International Standard Serial Number (ISSN)

0022-328X

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Elsevier, All rights reserved.

Publication Date

01 Jul 1973