Parametric Sensitivity Comparison of the BET and Dubinin-Radushkevich Models for Determining Char Surface Area by CO2 Adsorption
Abstract
The Formulation and Performance of Two Adsorption Models, the Brunauer, Emmett and Teller (BET) and the Dubinin and Radushkevich (DR), Are Compared. Surface Areas of Several Carbonaceous Samples (Coals and Chars) Were Determined by Applying Both the BET and DR Models to Data Obtained When Adsorbing Carbon Dioxide at 273 K. Sensitivity Analyses Indicate that the DR Model Should Have Less Propagation of Error from Experimental Measurements. However, the 'goodness of Fit' of the Experimental Data Tested Indicated that the BET Model Correlated the Data Better. Both Adsorption Models Correlated the Experimental Data Well (R2 > 0.9), Although the BET Model Consistently Gave a Better Fit to the Data. © 1992.
Recommended Citation
J. L. Sobolik et al., "Parametric Sensitivity Comparison of the BET and Dubinin-Radushkevich Models for Determining Char Surface Area by CO2 Adsorption," Fuel, vol. 71, no. 10, pp. 1195 - 1202, Elsevier, Jan 1992.
The definitive version is available at https://doi.org/10.1016/0016-2361(92)90101-S
Department(s)
Chemical and Biochemical Engineering
Keywords and Phrases
carbonaceous samples; char; surface area
International Standard Serial Number (ISSN)
0016-2361
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Elsevier, All rights reserved.
Publication Date
01 Jan 1992