Parametric Sensitivity Comparison of the BET and Dubinin-Radushkevich Models for Determining Char Surface Area by CO2 Adsorption

Abstract

The Formulation and Performance of Two Adsorption Models, the Brunauer, Emmett and Teller (BET) and the Dubinin and Radushkevich (DR), Are Compared. Surface Areas of Several Carbonaceous Samples (Coals and Chars) Were Determined by Applying Both the BET and DR Models to Data Obtained When Adsorbing Carbon Dioxide at 273 K. Sensitivity Analyses Indicate that the DR Model Should Have Less Propagation of Error from Experimental Measurements. However, the 'goodness of Fit' of the Experimental Data Tested Indicated that the BET Model Correlated the Data Better. Both Adsorption Models Correlated the Experimental Data Well (R2 > 0.9), Although the BET Model Consistently Gave a Better Fit to the Data. © 1992.

Department(s)

Chemical and Biochemical Engineering

Keywords and Phrases

carbonaceous samples; char; surface area

International Standard Serial Number (ISSN)

0016-2361

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Elsevier, All rights reserved.

Publication Date

01 Jan 1992

Share

 
COinS