Abstract
Glass ionomer cements (GICs) have potential orthopaedic applications. Solgel processing is reported as having advantages over the traditional melt-quench route for synthesizing the glass phase of GICs, including far lower processing temperatures and higher levels of glass purity and homogeneity. This work investigates a novel glass formulation, BT 101 (0.48 SiO2-0.36 ZnO-0.12 CaO-0.04 SrO) produced by both the melt-quench and the solgel route. The glass phase was characterized by X-ray diffraction (XRD) to determine whether the material was amorphous and differential thermal analysis (DTA) to measure the glass transition temperature (Tg). Particle size analysis (PSA) was used to determine the mean particle size and X-ray photoelectron spectroscopy (XPS) was used to investigate the structure and composition of the glass. Both glasses, the melt-quench BT 101 and the solgel BT 101, were mixed with 50 wt% polyacrylic acid (Mw, 80,800) and water to form a GIC and the working time (Tw) and the setting time (Ts) of the resultant cements were then determined. The cement based on the solgel glass had a longer Tw (78 s) as compared to the cement based on the melt derived glass (19 s). Ts was also much longer for the cement based on the solgel (1,644 s) glass than for the cement based on the melt-derived glass (25 s). The cements based on the melt derived glass produced higher strengths in both compression (σc) and biaxial flexure (σf), where the highest strength was found to be 63 MPa in compression, at both 1 and 7 days. The differences in setting and mechanical properties can be associated to structural differences within the glass as determined by XPS which revealed the absence of Ca in the solgel system and a much greater concentration of bridging oxygens (BO) as compared to the melt-derived system. © 2009 Springer Science+Business Media, LLC.
Recommended Citation
A. Wren et al., "The Effect of Glass Synthesis Route on Mechanical and Physical Properties of Resultant Glass Ionomer Cements," Journal of Materials Science: Materials in Medicine, vol. 20, no. 10, pp. 1991 - 1999, Springer, Oct 2009.
The definitive version is available at https://doi.org/10.1007/s10856-009-3781-6
Department(s)
Chemical and Biochemical Engineering
International Standard Serial Number (ISSN)
0957-4530
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2023 The Authors, All rights reserved.
Creative Commons Licensing
This work is licensed under a Creative Commons Attribution 4.0 License.
Publication Date
01 Oct 2009
PubMed ID
19459033
Included in
Biochemical and Biomolecular Engineering Commons, Biomedical Devices and Instrumentation Commons
