Synthesis of Glycosyl Α-Amino Acids

Author

Karl Bischofberger
Richard H. Hall, Missouri University of Science and TechnologyFollow
Amor Jordan

Abstract

The Major Isomer, (E)-1,4-Anhydro-1-Ethoxy-Carbonyl(Formylamino)methylene- 2,3 : 5,6-DiO-Isopropyl-Idene-D-Mannitol (2), Obtained by the Reaction of Α-Metallated Ethyl Isocyanoacetate with 2,3 : 5,6-Di-O-Isopropylidene-D- Mannono-1,4-Lactone, Gives on Hydrogenation and Acidic Hydrolysis, 2-L-(And 2-D-)(Β-D-Mannofuranosyl)glycines (10) and (11), and Can Be Converted into 2-L- and 2-D-(Β-D-Lyxofuransyl)glycines (12) and (13).

Recommended Citation

Bischofberger, K., Hall, R. H., & Jordan, A. (1975). Synthesis of Glycosyl Α-Amino Acids. Journal of the Chemical Society, Chemical Communications(19), pp. 806-807. Royal Society of Chemistry.

The definitive version is available at https://doi.org/10.1039/C39750000806

Department(s)

Business and Information Technology

Comments

National Science Foundation, Grant CTS000003N

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 1975