Synthesis of an Analogue of the Polyoxins. X-Ray Structure of Starting Carbohydrate and Acetal Migration Accompanying Acetolysis

Author

A. J. Brink
J. Coetzer
O. G. De Villiers
R. (Richard) H. Hall, Missouri University of Science and TechnologyFollow
A. Jordaan
G. J. Kruger

Abstract

An Analogue of the Polyoxins Has Been Prepared from 1,5 - Di - O - Acetyl - 3 - C - (R) - Ethoxycarbonylmethyl -5(R),1′(R) - N - Formylepimino - 2,3 - O - Isopropylidene - Β - D - Ribofuranose (13). the Structure of 13 Was Determined by X-Ray Analysis. Intramolecular Acetal Migrations Were Observed during Acetolysis under Acid Conditions. © 1976.

Recommended Citation

Brink, A. J., Coetzer, J., De Villiers, O. G., Hall, R. H., Jordaan, A., & Kruger, G. J. (1976). Synthesis of an Analogue of the Polyoxins. X-Ray Structure of Starting Carbohydrate and Acetal Migration Accompanying Acetolysis. Tetrahedron, 32(8), pp. 965-968. Elsevier.

The definitive version is available at https://doi.org/10.1016/0040-4020(76)85058-2

Department(s)

Business and Information Technology

International Standard Serial Number (ISSN)

0040-4020

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Elsevier, All rights reserved.

Publication Date

01 Jan 1976