Preparation of Analogues of the Carbohydrate Moiety of the Polyoxins

Abstract

Syntheses of 2-C-[Ethoxycarbonyl(Formylamino)methylene] Carbohydrate Derivates by Formylaminomethylenation of Two Pentofuranosulosides and a Pentopyranosuloside Are Described. Hydrogenation of the Unsaturated Branched-Chain Compounds Gave Glycosides Bearing Protected Amino-Acid Moieties as Substituents at C-2. Hydrolysis and Reduction Experiments that Establish the Structures of the Branched-Chain Compounds Are Described.

Department(s)

Business and Information Technology

International Standard Serial Number (ISSN)

1472-7781

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 1977

PubMed ID

560390

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