Preparation of Analogues of the Carbohydrate Moiety of the Polyoxins
Abstract
Syntheses of 2-C-[Ethoxycarbonyl(Formylamino)methylene] Carbohydrate Derivates by Formylaminomethylenation of Two Pentofuranosulosides and a Pentopyranosuloside Are Described. Hydrogenation of the Unsaturated Branched-Chain Compounds Gave Glycosides Bearing Protected Amino-Acid Moieties as Substituents at C-2. Hydrolysis and Reduction Experiments that Establish the Structures of the Branched-Chain Compounds Are Described.
Recommended Citation
Bischofberger, K., Brink, A. J., De Villiers, O. G., Hall, R. H., & Jordaan, A. (1977). Preparation of Analogues of the Carbohydrate Moiety of the Polyoxins. Journal of the Chemical Society, Perkin Transactions 1(12), pp. 1472-1476. Royal Society of Chemistry.
The definitive version is available at https://doi.org/10.1039/p19770001472
Department(s)
Business and Information Technology
International Standard Serial Number (ISSN)
1472-7781
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Royal Society of Chemistry, All rights reserved.
Publication Date
01 Jan 1977
PubMed ID
560390