Masters Theses
Abstract
"The physical properties and alkaline corrosion resistant properties of calcium-iron-phosphate glasses were studied. The addition of Fe₂O₃ decreases the thermal expansion coefficient and increases the glass fiber's Young's modulus in comparison with the addition of CaO. Bulk glass dissolution behavior in alkaline Lawrence solution was studied by weight loss experiments, Raman spectroscopy, and analytical scanning electron microscopy. The corrosion of glass powder in NaOH solution was studied by X-ray diffraction, infrared spectroscopy and high pressure liquid chromatography. The results show that the dissolution rate decreases when the phosphate chain length decreases. Calcium oxide can improve the glass durability in high pH solutions in comparison with ferric oxide. Phase equilibrium modeling was used to explain the formation of corrosion products, including hydroxyl apatite and Fe₂O₃"--Abstract, page iii.
Advisor(s)
Brow, Richard K.
Committee Member(s)
OKeefe, Matt
Day, D. E.
Department(s)
Materials Science and Engineering
Degree Name
M.S. in Ceramic Engineering
Publisher
University of Missouri--Rolla
Publication Date
Fall 2007
Pagination
x, 55 pages
Rights
© 2007 Jiawanjun Shi, All rights reserved.
Document Type
Thesis - Open Access
File Type
text
Language
English
Subject Headings
Calcium phosphate
Fiber-reinforced concrete
Glass -- Corrosion
Glass fibers
Thesis Number
T 9280
Print OCLC #
234477030
Electronic OCLC #
213883420
Link to Catalog Record
Recommended Citation
Shi, Jiawanjun, "Properties of alkaline-resistant calcium-iron-phosphate glasses" (2007). Masters Theses. 6828.
https://scholarsmine.mst.edu/masters_theses/6828
