"The electrochemical reduction of BrO⁻₃ was studied on a stationary Hg electrode in neutral and basic solutions containing K⁺, Na⁺, and L⁺. Coulombic efficiency studies showed Br⁻ to be the predominant reduction product. The steady state kinetic parameters include Tafel slopes of ca. -0.120 V, approximate first order activity dependences for both BrO⁻₃ and the accompanying cation, and no pH dependence. A reaction scheme is proposed which involves BrO⁻₃ "bridged" to the electrode by the accompanying cation. It is suggested that the "bridging" is a result of ion-pairing in the electrical double-layer"--Abstract, page 1.
Johnson, James W., 1930-2002
Strunk, Mailand R., 1919-2008
James, William Joseph
Mayhan, Kenneth G.
Chemical and Biochemical Engineering
Ph. D. in Chemical Engineering
University of Missouri--Rolla
viii, 79 pages
© 1973 Jaw-Shin Chang, All rights reserved.
Dissertation - Restricted Access
Library of Congress Subject Headings
Bromate -- Analysis
Reaction mechanisms (Chemistry) -- Design
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Link to Catalog Record
Electronic access to the full-text of this document is restricted to Missouri S&T users. Otherwise, request this publication directly from Missouri S&T Library or contact your local library.http://laurel.lso.missouri.edu/record=b1066485~S5
Chang, Jaw-Shin, "Electro-reduction of bromate on mercury" (1973). Doctoral Dissertations. 201.
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