An Arene-stabilized Cobalt(I) Aryl: Reactions with CO and NO
The half-sandwich cobalt(I) complex (η 6-C 7H 8)CoAr*-3,5- iPr 2 (Ar*-3,5- iPr 2 = -C 6H-2,6-(C 6H 2-2,4,6- iPr 3) 2-3,5- iPr 2) was synthesized by reduction of [3,5- iPr 2Ar*Co(μ-Cl)] 2 in toluene. It reacts with CO or NO to afford the unusual complexes [3,5- iPr 2Ar*C(O)Co(CO)] or [3,5- iPr 2Ar* N(NO)OCo(NO) 2]. © 2008 American Chemical Society.
H. Lei et al., "An Arene-stabilized Cobalt(I) Aryl: Reactions with CO and NO," Inorganic Chemistry, American Chemical Society (ACS), Jan 2008.
The definitive version is available at http://dx.doi.org/10.1021/ic8015782
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© 2008 American Chemical Society (ACS), All rights reserved.