Title

Analysis of Oxidation Byproducts of Dyfonate in Various Oxidant Systems using High Performance Liquid Chromatography Coupled with Quadrupole Ion Trap Mass Spectrometry

Abstract

Dyfonate is a dithiophosphonate pesticide used to control lepidopterous insects in corn, potatoes, and peanuts. It may be transferred to the surface water and underground water system and can be degraded by free chlorine and other oxidants, which are used by water treatment plants during the disinfection process, to produce oxidation byproducts. These byproducts may be more toxic than their parent compounds. Therefore, it is crucially important to identify these byproducts during the water treatment for full scale removal of them. In this article, a high pressure liquid chromatography/mass spectrometry (HPLC/MS) method was developed to investigate the oxidation byproducts of dyfonate by free chlorine (Cl2), hydrogen peroxide (H2O2), monochloroamine (MCA), chlorine dioxide (ClO2), Ozone (O3), and permanganate in an aqueous buffer (pH 7). Thin layer chromatography (TLC) and nuclear magnetic resonance (NMR) were also used for structure confirmation of the byproduct that was identified through HPLC/MS. One byproduct, dyfonate oxygen analog (phosphonothioic acid) was identified as the primary oxidation byproduct for free chlorine, ozone, MCA, and the H2O2 system, while no oxidation byproduct was detected in the ClO2 and permanganate system. The results of this study can serve as a valuable reference for water treatment plants.

Department(s)

Chemistry

Second Department

Civil, Architectural and Environmental Engineering

Keywords and Phrases

Aqueous Buffer; Chlorine Dioxides; Disinfection Process; Free Chlorine; Full Scale; High-pressure Liquid; HPLC/MS; HPLC/MS/MS; NO Oxidation; Oxidation By-products; Parent Compounds; Quadrupole Ion Traps; Structure Confirmation; Underground Water System; Acids; Byproducts; Chlorine; Chromatographic Analysis; Groundwater; High Performance Liquid Chromatography; High Pressure Liquid Chromatography; Hydrogen Peroxide; Liquids; Magnetic Logic Devices; Mass Spectrometry; Nuclear Magnetic Resonance; Nuclear Magnetic Resonance Spectroscopy; Oxidants; Oxidation; Ozone; Resonance; Thin Layer Chromatography; Water Recycling; Water Treatment Plants; Chemicals Removal (Water Treatment); Disinfection; Liquid Chromatography; Mass Spectrometry; Nuclear Magnetic Resonance; Oxidant; Oxidation; Pest Control; Pesticide; Arachis Hypogaea; Hexapoda; Solanum Tuberosum; Zea Mays

International Standard Serial Number (ISSN)

02772248

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2010 Taylor & Francis, All rights reserved.


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