Nanoparticles Produced by Laser Ablation of HfS₃ in Liquid Medium: Inorganic Fullerene-like Structures of Hf₂
Inorganic fullerene-like structures (IF) of the layered hafnium sulfide, Hf2S, have been synthesized by the laser ablation of HfS3 in tert-butyl disulfide medium. Apart from the Hf2S IFs exhibiting quasi-spherical as well as faceted nested-shell geometries, quasi-spherical nanoparticles of HfS were observed by this means. Whereas Hf2S has anti-NbS2 structure with S layers sandwiched between two Hf layers, HfS has the nonlayered WC-type structure. The nanoparticles of HfS show excess sulfur in the core, and they do not possess closed-shell geometry. The mechanism of formation of these nanoparticles has also been discussed.
M. Nath et al., "Nanoparticles Produced by Laser Ablation of HfS₃ in Liquid Medium: Inorganic Fullerene-like Structures of Hf₂," Chemistry of Materials, vol. 16, no. 11, pp. 2238-2243, American Chemical Society (ACS), Jun 2004.
The definitive version is available at https://doi.org/10.1021/cm035246s
Keywords and Phrases
Crystal Structure; Fullerenes; Hafnium Compounds; Laser Ablation; Synthesis (chemical); Hafnium Sulfide; Inorganic Fullerene (IF); Nanostructured Materials; Niobium; Sulfide; Sulfur; Unclassified Drug; aqueous Solution; chemical Structure; Geometry; Inorganic Chemistry; Laser; Nanoparticle; Reaction Analysis; Structure Analysis; Synthesis; Transmission Electron Microscopy
International Standard Serial Number (ISSN)
Article - Journal
© 2004 American Chemical Society (ACS), All rights reserved.