Title

Synthesis and Hydrolytic Stability of Tert-Butoxydimethylsilyl Enol Ethers

Abstract

tert-Butoxydimethylsilyl enol ethers derived from aldehydes and ketones were synthesized in good yields with high regioand stereoselectivities, under thermodynamically and kinetically controlled conditions. The hydrolytic stability of tert-butoxydimethylsilyl enol ether of cyclohexanone was studied under acidic and basic conditions and compared to that of trimethylsilyl, tert-butyldimethylsilyl and (2,4,6-tri-tert-butylphenoxy) dimethylsilyl enol ethers.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2001 Taylor & Francis, All rights reserved.


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