Synthesis and Hydrolytic Stability of Tert-Butoxydimethylsilyl Enol Ethers
tert-Butoxydimethylsilyl enol ethers derived from aldehydes and ketones were synthesized in good yields with high regioand stereoselectivities, under thermodynamically and kinetically controlled conditions. The hydrolytic stability of tert-butoxydimethylsilyl enol ether of cyclohexanone was studied under acidic and basic conditions and compared to that of trimethylsilyl, tert-butyldimethylsilyl and (2,4,6-tri-tert-butylphenoxy) dimethylsilyl enol ethers.
Z. A. Fataftah et al., "Synthesis and Hydrolytic Stability of Tert-Butoxydimethylsilyl Enol Ethers," Synthetic Communications, Taylor & Francis, Jan 2001.
The definitive version is available at http://dx.doi.org/10.1081/SCC-100104840
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