Title

Multifurcated Halogen Bonding Involving Ph-Cl⋯H-CPh=N-R' Interactions and Its Relation to Idioteloamphiphile Layer Architecture

Abstract

The presence of halogen bonding between a chloroarene and an aldazine C-H bond, i.e. Ph-Cl⋯H-CPh=N-R', makes all the difference in the crystal structure of 4-chlorobenzaldazine (1, R = H) and causes an idioteloamphiphile layer architecture (flat with longitudinal offset) that features multifurcated halogen bonding and that differs drastically from the one in 4-chloroacetophenone azine (2, R = CH3).

Department(s)

Chemistry

International Standard Serial Number (ISSN)

1466-8033

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2006 Royal Society of Chemistry, All rights reserved.

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