Title

A New Type of Polycyclophosphidochromium Cluster, [(Cp)Cr(CO)₂]₅P₁₀ (Cp = Η⁵-C₅H₅)

Alternative Title

First observation of polycylic P-to-M coordination

Abstract

The co-thermolysis of [(Cp)Cr(CO)3]2 (Cp = η5-C5H5) with P4 forms [(Cp)Cr(CO)2]5P10, a new paramagnetic structure with a P10 core, which represents the first example of polycyclic phosphorus-to-metal coordination.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1990 Royal Society of Chemistry, All rights reserved.


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