Organically Templated Mixed-Valent Iron-Sulfates Possessing Kagome and Other Types of Layered Networks
A perfect Kagomé lattice is displayed by the mixed-valent layered structure of [HN(CH2)6NH][FeIII- Fe2IIF6(SO4)2] · [H3O] (see picture), in which 100% of the iron sites are occupied. The complex exhibits unusual magnetic properties and both magnetic frustration and ferrimagnetic behavior are observed.
G. L. Paul et al., "Organically Templated Mixed-Valent Iron-Sulfates Possessing Kagome and Other Types of Layered Networks," Angewandte Chemie International Edition, vol. 41, no. 22, pp. 4297-4300, Wiley-VCH Verlag, Nov 2002.
The definitive version is available at http://dx.doi.org/10.1002/1521-3773(20021115)41:22<4297::AID-ANIE4297>3.0.CO;2-E
Keywords and Phrases
Crystal lattices; Iron compounds; Magnetic properties, Layered networks, Organic compounds, ferromagnetic material; ferrous sulfate, article; chemical analysis; chemical structure; complex formation; magnetism; materials testing; structure analysis; Hydrothermal synthesis; Iron; KagomÃ© lattice; Layered structures; Magnetic properties
International Standard Serial Number (ISSN)
Article - Journal
© 2002 Wiley-VCH Verlag, All rights reserved.