Organically Templated Mixed-valent Iron-sulfates Possessing Kagome and Other Types of Layered Networks
A perfect Kagomé lattice is displayed by the mixed-valent layered structure of [HN(CH2)6NH][FeIIIFeF6(SO4)2]⋅[H3O] (see picture), in which 100 % of the iron sites are occupied. the complex exhibits unusual magnetic properties; both magnetic frustration and ferrimagnetic behavior are observed.
A. Choudhury et al., "Organically Templated Mixed-valent Iron-sulfates Possessing Kagome and Other Types of Layered Networks," Angewandte Chemie International Edition, Wiley-VCH Verlag, Jan 2002.
The definitive version is available at http://dx.doi.org/10.1002/1521-3773(20021115)41:22<4297
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© 2002 Wiley-VCH Verlag, All rights reserved.